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Pure Appl. Chem., Vol. 68, No.5, pp. 1167-1193, 1996

Glossary of Terms Relatings to Pesticides

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quantitative structure-activity relationship (QSAR) Quantitative association between the physio-chemical properties of a pesticide or the properties of its molecular substructures and its biological properties including its non-target toxicity.

random sample Sub-set of a sampling population that is arrived at by selecting units such that each possible unit has a fixed and determinate probability of selection.

raw agricultural commodity Part of a crop used as a food or feed commodity directly from the harvested crop without processing.

raw data All original laboratory records and documentation, or verified copies thereof, including data directly entered in a computer. They are the results from the original activities and observations in a GLP study.

recovery, analytical Fraction or percentage of a pesticide residue recoverable following extraction and analysis of a matrix containing the pesticide. (after Gold et al, 1987)

redox potential Electrical potential indicating the relative activity of oxidised and reduced species. The redox potential of an environmental matrix is a measure of the extent to which oxidising species are present to act as terminal electron acceptors in respiration.

re-entry interval Minimum time between pesticide application and human re-entry to a treated area. Established by a regulatory authority to assure safety of workers from exposure to residues.

reference dose Expected dose resulting from human exposure to a pesticide at the level at which it is regulated in the environment. (US-EPA, 1992). See also acceptable daily intake, tolerable daily intake.

reference material Material or substance containing pesticide of interest at levels sufficiently homogenous and well characterised to be used for the calibration of an apparatus or assessment of analytical method performance. (after Thompson and Wood, 1995). See also certified reference material.

registration The process whereby the responsible national government authority approves the sale and use of a pesticide following the evaluation of scientific data demonstrating that the pesticide is effective for the purposes intended and not unduly hazardous to human or animal health or the environment. (FAO, 1986)

regulatory method Validated analytical method which can be applied using commonly available laboratory equipment and instrumentation. A regulatory method has the precision, specificity, limit of determination, etc, needed to test compliance with the regulations.

repeatability For an analytical method, the closeness of agreement between results of measurements on identical test material subject to the following conditions: same analyst, same instrumentation, same location, same conditions of use, repetition over a short period of time. (after Metrology, 1984)

reproducibility For an analytical method, the closeness of agreement between results of measurements on identical test material where individual measurements are carried under changing conditions such as: analyst, instrumentation, location, conditions of use, time. (after Metrology, 1984)

resistance Development of tolerance to a pesticide by a target population, generally through natural selection.

respiration Energy-generating process in an organism where an organic or inorganic compound serves as the electron donor and an inorganic compound (e.g. oxygen) serves as the electron acceptor.

retention sample Sample which is stored for a specified period in case of a need for re-evaluation of data obtained from the main laboratory samples.

risk Probability of any defined hazard occurring from exposure to a pesticide under specific conditions. Risk is a function of the likelihood of exposure and the likelihood to harm biological or other systems. See also hazard.

risk assessment Process of defining the risk associated with a specified use pattern for a pesticide, usually expressed as a numerical probability or as a margin of safety. Quantifying risk ideally requires,

  1. identification of hazard,
  2. establishment of dose-response relationships in likely target individuals and populations,
  3. exposure assessment (using likely exposure patterns as opposed to worst-case estimates).
    (after Duffus, 1993)


risk management Decision-making process and procedures used by regulators and others to limit potential risks from use of pesticides. This involves risk assessment, emission control, exposure control and evaluation of the success of the risk mitigation efforts.

rotational crop Crop grown in sequence of two or more different crops.

run-off

  1. Movement of a pesticide from a treated field by surface water and eroding sediment.
  2. Loss of formulation off foliage during spray application, particularly at high volume.

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