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Pure Appl. Chem., Vol. 68, No.5, pp. 1167-1193, 1996

Glossary of terms relatings to pesticides

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abiotic degradation Degradation of a pesticide via purely physical or chemical mechanisms. Examples include hydrolysis and photolysis.

absorption Transfer of a component from one phase to another (Gold, 1987). Movement of a pesticide from the environment (e.g. water, ingested food, leaf surface) across a biological membrane into an organism.

acceptable daily intake (ADI) Estimate of the amount of a pesticide in food and drinking water which can be ingested daily over a lifetime by humans without appreciable health risk. It is usually expressed in milligrams per kilogram of body weight. See also Tolerable daily intake. (after Duffus, 1993)

action level (regulatory) 1. For food commodities, an administrative maximum residue limit (MRL) used by regulatory authorities to initiate action where no legally defined MRL has been established. 2. For the environment, concentration of a pesticide in air, soil or water at which emergency measures or preventative actions are to be taken. (after Duffus, 1993)

action limits (analytical quality control) Limits for measurements on reference material or spiked samples which indicate when an analytical procedure is not performing adequately and requires immediate action before data can be reported.

active ingredient (ai) Pesticide present in a formulation as described by the common name. The part of a pesticide formulation from which the biological effect is obtained. (FAO, 1995)

accuracy (of measurement) Closeness of agreement between the result of a measurement and the (conventional) true value of the measurement. Note 1. Use of the term precision for accuracy should be avoided. Note 2. True value is an ideal concept and, in general, cannot be known exactly. (Metrology, 1984)

acute toxicity Ability of a substance to cause adverse effects within a short period following dosing or exposure. (after Duffus, 1993)

adjuvant Formulant designed to enhance the activity or other properties of a pesticide mixture.

adsorption Enrichment of one or more components in an interfacial layer. (Gold 1987)

adverse effect Change in morphology, physiology, growth development or lifespan of an organism which results in impairment of functional capacity or which increases susceptibility to the harmful effects of other environmental influences. (after IPCS, 1978)

aerobic Conditions under which molecular oxygen serves as the terminal electron acceptor in respiration or in metabolic oxygenation. See also redox potential. (after Gold, 1987)

aerosol System of fine solid or liquid particles (<30m m diam.) dispersed in a gas. Aerosol cans using an inert compressed propellant are a common means of dispensing insecticides for domestic use. See also nebulisation.

AFID Alkali flame-ionisation detector or detection for gas chromatography (cf NPD and TID).

aged residue Pesticide and degradates present in an environmental system after application and following a period long enough to allow transport, adsorption, metabolism, and dissipation processes to alter the distribution and chemical nature of some of the applied pesticide.

aggregate sample Sample made up of set proportions of other samples, typically an average by weight. See also composite sample.

aglycon Non-sugar part of a glycoside or glucuronide conjugate derived from the pesticide. See also exocon.

agrochemical Agricultural chemical used in crop and food production including pesticide, feed additive, veterinary drug and related compounds.

aliquot Known fractional portion of a homogeneous material (Horwitz, 1990). The term is usually applied to volumetric sub-sampling of fluids.

anaerobic Condition under which reductive conditions prevail. See also redox potential.

analytical portion See test portion.

analytical sample See test sample.

analytical range Measurement range of a test method where the performance has been validated and quality standards such as action limits have been developed.

analytical standard (pesticide) Pesticide reference material of high and defined purity (generally > 95%) for preparation of calibration standards.


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