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Pure Appl. Chem., Vol. 68, No.5, pp. 1167-1193, 1996

Glossary of Terms Relatings to Pesticides

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half-life (t0.5) Time taken for the concentration of a pesticide in a compartment to decline by one half. Usually an estimate based on observed dissipation over several half-lives that can be described by first order kinetics with rate constant k, t0.5 = 0.693/k. See also dissipation time 50%.

hazard Set of inherent properties of a pesticide which gives potential for adverse effects to man or the environment under conditions of its production, use or disposal, and depending on the degree of exposure. (after Duffus, 1993)

hazard assessment Determination of factors controlling the likely effects of a hazard such as mechanism of toxicity, dose-effect relationships and worst case exposure levels. This is the prelude to risk assessment. (US-EPA, 1992)

hazardous distance for the most sensitive effect (HDSE) Statistically determined safety margin corresponding to a distance from treated areas at which protection of the terrestrial environment can be adequately achieved as measured by the most sensitive non-target species. See also buffer zone, margin of safety.

health advisory level (HAL) Estimate of upper concentration limit for a pesticide in drinking water that can be consumed for a lifetime without adverse effects. HALs generally do not have formal legal significance but have been used, particularly in the USA, for preliminary risk assessment.

HPLC High performance liquid chromatography.

HPTLC High performance thin layer chromatography.

HRGC High resolution gas chromatography (GLC with narrow bore capillary columns).

hydrolysis Reaction in which a chemical bond is cleaved and a new bond formed with the oxygen atom of a molecule of water.


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