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Pure Appl. Chem., Vol. 68, No.5, pp. 1167-1193, 1996

Glossary of Terms Relatings to Pesticides

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laboratory sample Sample or subsample(s) sent to or received by the laboratory.

lag phase Period which may precede commencement of rapid degradation of a pesticide by a microbial population. It is the period needed either for induction of microbial enzymes or for growth of the microbial population to adequate size. See also enhanced degradation. (after US-EPA, 1992)

LC50 See median lethal concentration.

LD50 See median lethal dose.

leaching Process by which a pesticide moves downward through the soil profile in the aqueous phase.

leachate Aqueous phase percolating through a soil profile or a soil column.

limit of detection (LOD) Lowest concentration of a pesticide residue in a defined matrix where positive identification can be achieved using a specified method.

limit of quantitation (LOQ) Lowest concentration of a pesticide residue in a defined matrix where positive identification and quantitative measurement can be achieved using a specified method. The term limit of quantitation is preferred to limit of determination to differentiate it from LOD. LOQ has been defined as 3 times the LOD (Keith, 1991) or as 50% above the lowest fortification level used to validate the method (US-EPA, 1986).

limit of reporting Practical limit of residue quantitation at or above the LOQ. The limit of quantitation for a defined matrix and method may vary between laboratories or within the one laboratory from time to time because of different equipment, techniques and reagents.

lipophilicity Affinity for fat as described by partitioning behaviour between water and an immiscible organic solvent, favouring the latter, and which correlates with bioconcentration. See also octanol-water partition coefficient. (after Duffus, 1993)

lot Quantity of material which is assumed to be a single population for sampling purposes. See also batch.

lysimeter Device for measuring leaching losses from a column or block of soil. The simplest lysimeters may be devices for sampling a portion of the water leaching through a natural sediment or soil (e.g. suction lysimeter), whereas more elaborate lysimeters may involve the confinement of an entire segment of soil from which all leachate is collected (e.g. monolithic lysimeter).


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