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Pure Appl. Chem., Vol. 68, No.5, pp. 1167-1193, 1996

Glossary of Terms Relatings to Pesticides

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safener A substance added to a pesticide formulation to eliminate or reduce phytotoxic effects of the pesticide to certain crops. See also adjuvant.

safety factor See uncertainty factor.

sample Portion of material selected from a larger quantity of material so that it is representative of the whole. See also aggregate sample, aliquot, composite sample, control sample, increment sample, laboratory sample, primary sample, random sample, retention sample, subsample, test portion and test sample.

sampling plan Predetermined procedure for the selection, withdrawal, preservation, transportation, and preparation of the portions to be removed from a population as samples. (Horwitz, 1990)

SEC Size exclusion chromatography (cf GPC).

SFC Supercritical fluid chromatography.

SFE Supercritical fluid extraction.

soil partition coefficient (Kd) Experimental ratio of a pesticide's concentration in the soil to that in the aqueous (dissolved) phase at equilibrium. It is valid only for the specific concentration and solid/solution ratio of the test. The Kd is a distribution coefficient reflecting the relative affinity of a pesticide for adsorption by soil solids and its potential for leaching movement through soil. See also Koc.

soil incorporation Application of a pesticide to soil by mixing or injection into the soil body.

soil organic partition coefficient (Koc) Ratio of a pesticide concentration sorbed in the organic matter component of soil or sediment to that in the aqueous phase at equilibrium. The Koc is calculated by dividing the Kd value by the fraction organic carbon present in the soil or sediment (see soil organic matter).

soil organic matter Organic fraction of the soil, including both fresh and aged residues (e.g. humus) of biological origin. Organic carbon refers to that portion of the soil measured as carbon in organic forms, and the organic matter content of soil is assumed to be approximately 1.72-fold that of the organic carbon content.

sorption Removal of pesticide from solution by soil or sediment via mechanisms of adsorption and absorption.

SPE Solid phase extraction.

specimens Samples collected from a system for examination, analysis, or storage.

spiked sample (fortified sample) Control sample with a known amount of pesticide added. Used to test the accuracy (especially the efficiency of recovery) of an analytical method. (after Thompson and Wood, 1995). See also reference material.

spray drift Movement beyond the target area of airborne droplets or vapour of pesticide formulation originating from aerial or ground-based spraying operations.

spreader See wetting agent.

standard solution, primary Standard prepared by dissolving a weighed amount of an analytical standard pesticide in a known volume of solvent.

standard solution, secondary Standard prepared by dilution of an aliquot of a primary standard solution with a known volume of solvent, or by subsequent serial dilutions; or a standard solution measured by reference to a primary standard solution.

sticker Formulant which increases the adhesiveness of a formulation applied to a surface. (FAO, 1995). See also wetting agent.

storage stability test For a pesticide formulation, a test which measures the chemical and physical stability of the product stored under defined, often worst case, conditions. For pesticide residues, a test which measures stability of residues in stored analytical samples, usually held under frozen conditions at a specified temperature.

subsample

  1. portion of the sample obtained by selection or division;
  2. individual unit of the lot taken as part of the sample;
  3. final unit of multistage sampling. (Horwitz, 1990)

surfactant A formulant for reducing interfacial tension of two boundary surfaces, thereby increasing the emulsifying, spreading, dispersability or wetting properties of liquids or solids. (FAO, 1995.)

surveillance Systematic sampling and residue analysis of commodities, and collation and interpretation of data, in order to ensure compliance with established MRLs. Surveillance may be directed at domestic, imported or exported commodities.

suspension concentrate (SC) Formulation in which the active ingredient is in the form of a stable dispersion of fine particles in water or organic liquid. (GIFAP, 1989)

synergist Substance, which, while formally inactive or weakly active, can significantly enhance the activity of the active ingredient in a formulation.

systemic A systemic pesticide is capable of being translocated to sites other than where it was absorbed in sufficient quantities to be biologically effective.


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