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Pure Appl. Chem. 76(9), 1679-1689, 2004

Pure and Applied Chemistry

Vol. 76, Issue 9

Physicochemical and technological features of creating metal-based high-superalloys

E. N. Kablov and N. V. Petrushin

All-Russia Institute of Aviation Materials, 17 Radio St., Moscow 107005, Russia

Abstract: The analysis of modern nickel-based superalloys evolution for casting single-crystal turbine blades was performed. The influence of rhenium as a new alloying element on the physicochemical, kinetic, and structural parameters of nickel-based superalloys and phase stability is discussed. The following experimental data are generalized: the coefficients of segregation and distribution of alloying elements in nickel-based superalloys gamma- and gamma'-phases, the influence of alloying elements on the melting temperature, gamma- and gamma'-phases crystal lattice parameters, diffusion rate of atoms and probability of topologically close-packed (TCP) phase formation. The principles of the balanced alloying and computerized design method for developing fourth-generation single-crystal nickel-based superalloys with high Re content (9 �10 %) are considered. The role of high gradient directional solidification (200 �220�C cm�1) in producing single-crystal turbine blades of nickel-based superalloys with high Re content is discussed.

*Plenary lecture presented at the XVII Mendeleev Congress on General and Applied Chemistry, Kazan, Tatarstan, Russia, 21 -26 September 2003. Other presentations are published in this issue, pp. 1605-1798.


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