Organometallic
Chemistry Directed Towards Organic Synthesis
Plenary and invited lectures presented at the 12th
IUPAC International Symposium on Organometallic Chemistry Directed Towards
Organic Synthesis (OMCOS-12), Toronto, Ontario, Canada, 6-10 July 2003
Preface, W. Tam
Metal cyclopropyl carbenes in the reactions of alkynes with alkenes
and furans
A. M. Echavarren, M. M�ndez, M. P. Mu�oz, C. Nevado, B. Mart�n-Matute,
C. Nieto-Oberhuber, and D. J. C�rdenas
p. 453 [Abstract] [full
text - pdf 296KB]
Rhodium-catalyzed asymmetric addition of aryl- and alkenylboron reagents
to electron-deficient olefins
T. Hayashi
p. 465 [Abstract] [full
text - pdf 329KB]
Synthetic applications of planar chiral cationic nu3-allylmolybdenum
complexes
P. Kocienski, R. Bell, E. Bourque, J. A. Christopher, J. Cooksey,
A. Gunn, A. Kuhl, Y. Li, S. Uppal, and J. Yuen
p. 477 [Abstract] [full
text - pdf 334KB]
Application of allylic substitutions in natural products synthesis
G. Helmchen, M. Ernst, and G. Paradies
p. 495 [Abstract] [full
text - pdf 319KB]
Development of catalysts for the hydroamination of olefins
J. F. Hartwig
p. 507 [Abstract] [full
text - pdf 284KB]
New regio-, stereo-, diastereo- and enantioselective one-pot reactions
mediated by organometallic derivatives
N. Chinkov, G. Sklute, H. Chechik, A. Abramovitch, D. Amsallem,
J. Varghese, S. Majumdar, and I. Marek
p. 517 [Abstract] [full
text - pdf 485KB]
Negative nonlinear effect in aquo palladium catalysis depending on
tropos biphenylphosphine ligand chirality controlled by chiral diaminobinaphthyl
activator
K. Mikami, K. Aikawa, and M. Yamanaka
p. 537 [Abstract] [full
text - pdf 210KB]
Asymmetric catalytic synthesis of polyketones and polycarbonates
K. Nozaki
p. 541 [Abstract] [full
text - pdf 208KB]
Development of a new methodology for the preparation of optically
active alcohols
P. G. Andersson
p. 547 [Abstract] [full
text - pdf 201KB]
Stereochemistry of epoxide carbonylation using bimetallic Lewis acid/metal
carbonyl complexes
Y. D. Y. L. Getzler, V. Mahadevan, E. B. Lobkovsky, and G. W. Coates
p. 557 [Abstract] [full
text - pdf 243KB]
Dual role of nucleophiles in palladium-catalyzed Heck, Stille, and
Sonogashira reactions
A. Jutand
p. 565 [Abstract] [full
text - pdf 304KB]
Application of C-H and C-C bond activation in organic synthesis
C.-H. Jun and J. H. Lee
p. 577 [Abstract] [full
text - pdf 293KB]
Coordination of the Trost modular ligand to palladium allyl fragments:
Oligomers, monomers and memory effects in catalysis
G. C. Lloyd-Jones, S. C. Stephen, I. J. S. Fairlamb, A. Martorell,
B. Dominguez, P. M. Tomlin, M. Murray, J. M. Fernandez, J. C. Jeffery,
T. Riis-Johannessen, and T. Guerziz
p. 589 [Abstract] [full
text - pdf 270KB]
New methods for the synthesis of heterocyclic compounds
A. Caiazzo, S. Dalili, C. Picard, M. Sasaki, T. Siu, and A. K. Yudin
p. 603 [Abstract] [full
text - pdf 254KB]
Mechanistic insights into perfluoroaryl borane-catalyzed allylstannations:
Toward asymmetric induction with chiral boranes
D. J. Morrison, J. M. Blackwell, and W. E. Piers
p. 615 [Abstract] [full
text - pdf 254KB]
New insights into the mechanism of molybdenum-catalyzed asymmetric
alkylation
S. W. Krska, D. L. Hughes, R. A. Reamer, D. J. Mathre, M. Palucki,
N. Yasuda, Y. Sun, B. M. Trost
p. 625 [Abstract] [full
text - pdf 288KB]
Recent advances in catalyst immobilization using supercritical carbon
dioxide
W. Leitner
p. 635 [Abstract] [full
text - pdf 314KB]
Substrate scope in the olefin cyclopropanation reaction catalyzed
by m-oxo-bis[(salen)iron(III)] complexes
S. K. Edulji and S. T. Nguyen
p. 645 [Abstract] [full
text - pdf 158KB]
Recent advances in transition metal-catalyzed or -mediated cyclization
of 2,3-allenoic acids: New methodologies for the synthesis of butenolides
S. Ma
p. 651 [Abstract] [full
text - pdf 212KB]
3-Halopropenyl esters as precursors of a new class of oxygen-substituted
allylic organometallic compounds: Applications in organic synthesis
M. Lombardo, S. Licciulli, and C. Trombini
p. 657 [Abstract] [full
text - pdf 332KB]
Palladium-catalyzed alkylation of unactivated olefins
R. A. Widenhoefer
p. 671 [Abstract] [full
text - pdf 219KB]
Heterogeneous asymmetric catalysis
M. Lemaire
p. 679 [Abstract] [full
text - pdf 265KB]
Stereoselective chromium- and molybdenum-mediated transformations
of arenes
E. P. K�ndig, R. Cannas, C.-H. Fabritius, G. Grossheimann, M. Kondratenko,
M. Laxmisha, S. Pache, H. Ratni, F. Robvieux, P. Romanens, and S. Tchertchian
p. 689 [Abstract] [full
text - pdf 258KB]