New developments in radical chemistry. Applications to total synthesis
and asymmetric processes*
Christophe Aïssa, Bénédicte Delouvrié, Anne-Lise
Dhimane, Louis Fensterbank, and Max Malacria**
Université Pierre et Marie Curie, Laboratoire
de Chimie Organique de Synthèse, Tour 44-54, B. 229, 4, Place
Jussieu, 75252 Paris Cedex 05 France
Abstract: This article reviews our contribution in the field
of radical synthetic chemistry, focusing on cascades relying on the
use of propargylic BMDMS ethers and asymmetric synthesis using enantiopure
vinylsulfoxides.
*Lecture presented at the 13th International
Conference on Organic Synthesis (ICOS-13), Warsaw, Poland, 1-5 July
2000.
** Corresponding author: E-mail: [email protected]
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