Number: 2001-052-1-500 (previous 581/15/89)
Title: Solubility of volatile and gaseous fluorides in all solvents
Series: Solubility Data Series; editor-in-chief: Mark
Salomon
Task group
Chairman: H.L. Clever
Member: R. Battino
Completion Date: 2005 - project completed
Objective:
A critical evaluated collection of solubility data of the fluorides
of xenon, boron, nitrogen, sulfur and carbon in all solvents, including
XeF's, BF3, NF3, N2F4, SF6,
CF4, CHF3, CH2F2, CH3F,
C2F6, C2HF5, C2H2F4,
C2H3F3, C2H4F2,
C2H5F, C2F4, C2H2F2,
C2H3F, C3F8, C3F6,
c-C4F8, C2F6O (ether), C3F6O
(oxirane).
Description:
A literature search for solubility data of the compounds XeF6,
XeF4, XeF2, BF3, NF3, N2F4,
SF6, CF4, CHF3, CH2F2,
CH3F, C2F6, C2HF5,
C2H2F4, C2H3F3,
C2H4F2, C2H5F,
C3F8, c-C4F8, C2H3F,
C2H2F2, C2F4,
C3F6, SiF4 and a few other compounds
in all solvents is at least 85 % complete. So far approximately 350
systems have been compiled in rough draft and near 200 have been prepared
in final draft. For systems for which data are available from several
laboratories a critical evaluation will be prepared giving tables, equations
and figures showing the recommended and tentative data. The volume should
be of use to workers in environmental chemistry, industry, engineering
and theoreticians in solution theory.
Progress:
Status in Jan 2003 - Most data compilations are complete. There
is good progress on gas + water evaluations, other evaluations will
get underway soon. All recent papers between 1988 and 2002 (also covering
gas + seawater ) have been collected and will be included in the review.
Volume 80 in the IUPAC-NIST Solubility Data Series. is to be published
in J. Phys. Chem. Ref. Data 2005.
Published as Volume 80 in of the IUPAC-NIST Solubility Data Series.
in J. Phys. Chem. Ref. Data 2005, 34, No. 1, 201-438.
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Last Update: 29 June 2005