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ATTRACTION AND REPULSION

Gibbs energy of repulsion (between two surfaces)  $ G_r$
Gibbs energy of repulsion due to electric effects   $ G_{\text{el}}$
Gibbs energy of repulsion per unit area of two parallel plates  $ g_r$, $ g_{\text{el}}$
Gibbs energy of attraction of two surfaces  $ G_a$
Gibbs energy of attraction per unit area of two parallel plates  $ g_a$
Van der Waals-London attraction constant between two molecules ( $ ={\phi}r^6$)  $ {\lambda}$
(Van der Waals-)Hamaker constant between semi-infinite flat plates, distance $ h$ apart ($ n$ = number of molecules per unit volume) ( $ =-g_a{\cdot}12{\pi}h^2 = {\pi}^2n^2{\lambda}$)  $ A_H$
Retarded van der Waals constant between two molecules ( $ =-{\phi}r^7$)  $ {\beta}$
Retarded van der Waals constant between semi-infinite flat plates, distance $ h$ apart ( $ =-3g_ah^3 = (1/10){\pi}n^2{\beta}$)  $ B$
Total Gibbs energy of interaction (and per unit area of two parallel plates)  $ G_t(g_t)$
Disjoining pressure ( $ =-\mathrm{d}g_t/\mathrm{d}h$)  $ {\Pi}_d$

next up previous contents
Next: SEDIMENTATION, CREAMING, CENTRIFUGATION AND Up: LIST OF SYMBOLS AND Previous: COLLIGATlVE AND RELATED PROPERTIES   Contents
2002-09-05